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MaterialsScienceandEngineeringB152(2008)96–104 ContentslistsavailableatScienceDirect MaterialsScienceandEngineeringB journalhomepage:www.elsevier.com/locate/mseb Review Flexibleorganicelectronicdevices:Materials,processandapplications StergiosLogothetidis∗ LaboratoryforThinFilms-Nanosystems&Nanometrology,DepartmentofPhysics,AristotleUniversityofThessaloniki,Thessaloniki54124,Greece articleinfoabstract Keywords:Theresearchforthedevelopmentofflexibleorganicelectronicdevices(FEDs)israpidlyincreasing OLEDworldwide,sinceFEDswillchangeradicallyseveralaspectsofeverydaylife.Althoughtherehasbeen OPVconsiderableprogressintheareaofflexibleinorganicdevices(a-SiorsolutionprocessedSi),thereare Polymers numerousadvancesintheorganic(semiconducting,conductingandinsulating),inorganicandhybrid Organic (organic–inorganic)materialsthatexhibitcustomizedpropertiesandstability,andinthesynthesisand Spectroscopicellipsometry Roll-to-rollpreparationmethods,whicharecharacterizedbyasignificantamountofmultidisciplinaryefforts.Fur- thermore,thedevelopmentandencapsulationoforganicelectronicdevicesontoflexiblepolymeric substratesbylarge-scaleandlow-costroll-to-rollproductionprocesseswillallowtheirmarketimple- mentationinnumerousapplicationareas,includingdisplays,lighting,photovoltaics,radio-frequency identificationcircuitryandchemicalsensors,aswellastoanewgenerationofmodernexoticapplications. Inthiswork,wereportonsomeofthelatestadvancesinthefieldsofpolymericsubstrates,hybridbarrier layers,inorganicandorganicmaterialstobeusedasnovelactiveandfunctionalthinfilmsandnanoma- terialsaswellasfortheencapsulationofthematerialscomponentsfortheproductionofFEDs(flexible organiclight-emittingdiodes,andorganicphotovoltaics).Moreover,wewillemphasizeonthereal-time opticalmonitoringandcharacterizationofthegrowingfilmsontotheflexiblepolymericsubstratesby spectroscopicellipsometrymethods.Finally,thepotentialityforthein-linecharacterizationprocesses forthedevelopmentoforganicelectronicsmaterialswillbeemphasized,sinceitwi