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ProgressinMaterialsScience57(2012)660–723 ContentslistsavailableatSciVerseScienceDirect ProgressinMaterialsScience journalhomepage:www.elsevier.com/locate/pmatsci Fundamentals,processesandapplications ofhigh-permittivitypolymer–matrixcomposites ⇑ Zhi-MinDanga,b,c,,Jin-KaiYuanb,Jun-WeiZhaa,TaoZhoub, ⇑ Sheng-TaoLic,Guo-HuaHud,e, aDepartmentofPolymerScienceandEngineering,SchoolofChemicalandBiologicalEngineering, UniversityofScience&TechnologyBeijing,Beijing100083,China bStateKeyLaboratoryofChemicalResourceEngineering,BeijingUniversityofChemicalTechnology,Beijing100029,China cStateKeyLaboratoryofElectricalInsulationandPowerEquipment,Xi’anJiaotongUniversity,Xi’an710049,China dLaboratoryofReactionsandProcessEngineering,NancyUniversity,CNRS-ENSIC-INPL,1rueGrandville,B.P.451, 54001NancyCedex,France eInstitutUniversitairedeFrance,MaisondesUniversités,103BoulevardSaint-Michel,75005Paris,France articleinfoabstract Articlehistory:Thereisanincreasingneedforhigh-permittivity(high-k)materials Received21April2011duetorapiddevelopmentofelectrical/electronicindustry.Itis Receivedinrevisedform27May2011well-knownthatsinglecompositionmaterialscannotmeetthe Accepted14August2011 high-kneed.Thecombinationofdissimilarmaterialsisexpected Availableonline25August2011 tobeaneffectivewaytofabricatecompositeswithhigh-k,especial Abbreviations:Al2O3,alumina;BaTiO3,bariumtitanate;CB,carbonblack;CCTO,calciumcoppertitanate;CF,carbonfiber; CH2Cl2,dichlodomethylenechloride;CNF,carbonnanofiber;CNT,carbonnanotubes;CuPc,copper-phthalocyanine;DBSA, dodecylbenzenesulfonicacid;DMF,dimethylformamide;HA,hydroxyapatite;HDPE,high-densitypolyethylene;LDPE,low- densitypolyethylene;LTNO,LiandTicodopedNiO;MNCB,modifiednanoscalecarbonblack;MWNT,multi-wallcarbon nanotubes;NMP,N-methyl-pyrrolidone;ODA,4,40-oxydianiline;PA,polyamide;PAA,poly(amicacid);PANI,polyaniline; PbTiO3,leadtitanate;PC,polycarbonate;PCMS,poly(p-chloromethylstyrene);PE,polyethylene;PEEK,polyetheretherketone; PFSA,perfluorosulfonicacid;PHAE,p