有机化学专升本试题真题及答案.pdf

（A）（6,1,6）1-2CH3（CH2）14CH2N（CH3）3Br3OO4CH3CH2C-O-CCH35JCHO6CH3—S02Cl（11181CHCHCH=CHCHCHOAg（NH）N32232°3.（2KMnO4CH3CH2CH二CHCH2CHOCH2CICH2CN4153)H/Ni(CHCO)O------232►NaOHCH2O3CHO+CHCHO—23丿NaOH425CH3CH5CHCOOHOH32⑴LiAIH46(2)H2OCH2CH0KMnO714HOCH2COO2HOO⑴1111C2H5ONaCH3C(CH2)3COC2H5OBrZnCHCOOCH225H2O1911CHCCH/H+»(332O,HO-”NK（410）1OHCH3CH2CHCH2CH3(1)I(2)CHCH3OH（3）ICH2CHOCH3CH2CH2CHO2(2)I(1)CHCOCHCHOHCHOH323CHCHCHOHHO—f32OHCHO⑶CH335OHO(1)HC—cCH3—C3⑵XO4⑴(2)(3)(4)(6318)1(A)CHjCCHD(B)0)(C)CHJCCHJCHJ(D)(CH33COC(CHJ}30O2(A)(B)(C)N-(D)(E)3(B)(A)CH3COCH2COCH3CH3COCH2COOCH2CH3(D)()(C)CH3COCH2COC6H5CH2COOC2H524CHCONH(CHCO)O(A)32(B)CH3COOC2H5(C)32(D)CH3COC1(E)CH3COOH5(A)(B)(C)(D)456(C)(A)(B)(D)(39)(1)(C)(D)(A)2-(B)3-(2)((C)2-(D)(A)B)(E)(3)(210)1亠+-N2H2OOH2(1)55OCH/OHIIHCNCZCH3CCH3/XOH-CHCH2（5420）1（）22--2-3COOH4C4C45-CH3CH2(339)1AC8H9OBr65AA)B(C8H8O3BCCABC2(A)C7H9N(A)KOHCa(A)NaNO2HCI0~5-(B)(A)IR815cm-1(A)(B)3CHO20cm6103-150cm3-1=1.2(3H)3=2.2(3H)3=3.5(2H)3=4.1(2H)75（6,1,6）o231||CHBCCHQCHZCOOH（CH3CH2CH2CH2）2NH46or（1118）1CH3CH2CH=CHCH2COOH2CH3CH2COOH+HOOCCH2COOHCHCHNHCHCHNHCOCH222223NaCN13CH2COOHCH2COOC2H5))(HOCH23CCHOC(CH2OH54ClCl4CHC00HH2627_CH2C00HH2CHOH2OZnBrOH—CHg—9CH3c—CH2COOC2H53—1)CH2COOC2H5CH3CH385（）（）10N—CH2CH2CH3CH23CH34NH2（410）1（2）（3）2（2）（3）3（1）（2）4（2）（3）（）（6318）1ABC2BAC3CABEDD4DCE5DBC6ABD（39）2—rCHI3（）「「3—XX]B2/CCl4.、（（XlxNaHSO3）1）95(CH3CH2)2CHO［Fehling'sC6H5CHOIXJ(2)Tollen's「黄NaHSOCHCOCH-------3U325---------------►I+NaOHlx2C6H5COCH3IX（3）（（）HSO）24（）（210）1（1）（3）S1N；2COOCH3COOCH34——ONH2CH3HONHCH3COOCH3NHCH3N-CH3（5420）HNONHI3NO222HSO124105NaNO+HCIHpCOOH2J-N2CCuCN—CN0-----------------------►oKCN»--------0~5CBrBrBrOH2CH3MgBrH2OI2CH3CH2C00CH3CH3CH2—CH3CH33BrBr-+C2H5ONa-CH2CH2CH2CH2CH2(COOC2H5)2CH(COOC2H5)2-BrBrBrII--LCOOC2H5CH2CH2CH2CH2C(CH)CH(COOC)2H5H2232H52C°L^COOC2H5Na⑴NaOH/H2O^y^COOH⑶D-CO2OOOONCHCHCHBrIIIICHCHCOCH2H5S32243C-225C°ACH3C—CHCOC2H5CH2CH2CH3⑴5%NaOHOOH⑵H+H2CH3C—CH2CH2CH2CH3ACH3CHCH2CH2CH2CH3Ni⑶D-CO25OHNaNO,HCl2N=N0~5C（339）1151ABC0CH3OCH3OT(A)*^COOH(B)CHBrCOOH22（A）（B）OH