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TMPDCO对封端型水性聚氨酯的改性研究 Title:ResearchonModificationofBlockedIsocyanateWaterbornePolyurethane Abstract: Waterbornepolyurethane(WPU)isanovelclassofpolymersthathavegainedsignificantattentionduetotheiruniqueproperties,includinglowvolatileorganiccompoundemissions,environmentallyfriendlynature,andexceptionalmechanicalproperties.However,theapplicationofWPUisoftenlimitedduetoitsinferiorthermalstabilityandpoorcompatibilitywithsomesubstrates.Inrecentyears,modificationstrategiesusingblockedisocyanateshavebeenexploredtoimprovethesedrawbacks.Thispaperaimstoprovideanoverviewoftheresearchconductedonthemodificationofblockedisocyanatewaterbornepolyurethane. 1.Introduction 1.1Background 1.2Objective 2.WaterbornePolyurethane(WPU) 2.1SynthesisofWPU 2.2PropertiesandApplicationsofWPU 3.BlockedIsocyanateModification 3.1TypesofBlockedIsocyanates 3.2MechanismofBlockedIsocyanateModification 3.3AdvantagesandDisadvantagesofBlockedIsocyanateModification 4.MethodsofBlockedIsocyanateModification 4.1One-ComponentSystems 4.2Two-ComponentSystems 4.3CombinationStrategies 5.EffectofBlockedIsocyanateModification 5.1ThermalStabilityImprovement 5.2CompatibilityEnhancement 5.3MechanicalPropertyOptimization 6.ApplicationsofBlockedIsocyanateModifiedWPU 6.1CoatingApplications 6.2AdhesiveApplications 6.3OtherFunctionalApplications 7.FuturePerspectives 7.1EmergingTrendsinBlockedIsocyanateModification 7.2ChallengesandOpportunities 8.Conclusion References Inthisresearchpaper,thefocuswillbeonthemodificationofblockedisocyanateinwaterbornepolyurethane(WPU).ThismodificationtechniquehasshownpromisingresultsinimprovingthethermalstabilityandcompatibilityofWPUwithvarioussubstrates.Thepaperwilldiscussthevarioustypesofblockedisocyanates,theirmechanismsofmodification,andtheadvantagesanddisadvantagesassociatedwiththisapproach.Additionally,themethodsofblockedisocyanatemodification,suchasone-componentsystems,two-componentsystems,andcombinationstrategies,willbeexplored.Theimpactofblockedisocyanatemodificationonthermalstability,c