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济南市大气降尘地球化学特征及污染端元研究 Title:GeochemicalCharacteristicsandPollutionSourcesofAtmosphericDustfallinJinanCity Abstract: Atmosphericdustfallisanimportantcarrierofvariouspollutantsinurbanareas,whichcanposesignificantriskstohumanhealthandtheenvironment.TounderstandthegeochemicalcharacteristicsandpollutionsourcesofatmosphericdustfallinJinanCity,thisstudyconductedacomprehensiveinvestigationandanalysisofdustfallsamplescollectedfromdifferentregionswithinthecity.TheresultsshowedthatthedustfallinJinanCityprimarilyconsistedofcrustalelementssuchasSi,Al,andFe,aswellasanthropogenicpollutantsincludingheavymetals.Additionally,theconcentrationsofheavymetalsindustfallwerehigherinindustrialareascomparedtoresidentialareas.Thecombinationofgeochemicalanalysis,sourceapportionmentmodeling,andspatialdistributionmappingprovidedvaluableinformationforidentifyingandmanagingthesourcesofatmosphericpollutioninJinanCity. 1.Introduction Atmosphericdustfallreferstothedepositionofairborneparticlesontosurfacessuchasroofs,roads,andvegetation.Itcancarrynumerouspollutants,includingheavymetals,organiccompounds,andmicroorganisms,whichcanhaveadetrimentalimpactonhumanhealthandtheenvironment.JinanCity,thecapitalofShandongProvinceinChina,hasexperiencedrapidurbanizationandindustrializationinrecentdecades,leadingtoincreasedpollutionandenvironmentalconcerns.Therefore,understandingthegeochemicalcharacteristicsandpollutionsourcesofatmosphericdustfalliscrucialforeffectiveenvironmentalmanagementandpollutioncontrolinthecity. 2.Methodology 2.1SampleCollection DustfallsampleswerecollectedfromvariousdistrictsofJinanCityusingenameldishes,whichwereexposedoutdoorsforafixedperiod.Thesamplinglocationsincludedresidential,commercial,andindustrialareas,aswellassitesalongmajortrafficarteries.AtotalofXXsampleswerecollectedandtransportedtothelaboratoryforanalysis. 2.2GeochemicalAnalysis ThecollecteddustfallsampleswereanalyzedformajorandtraceelementsusingX-rayfluorescence(XRF)andinductivelycoupledplasmamassspectrometry(ICP-MS),respective