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多孔氮化硅陶瓷制备及其性能研究进展 摘要: 多孔氮化硅陶瓷是一种具有良好化学惰性、高温稳定性和优异的机械性能的新型材料,因此在众多领域有着广泛的应用前景。本文首先介绍多孔氮化硅陶瓷的制备方法,包括氮化硅前驱体制备、模板法制备和软硬模压制等方法,描述它们各自的优缺点。随后对多孔氮化硅陶瓷的物理性能、化学稳定性和应用前景进行了详细的讨论。最后,提出了进一步的研究方向和展望。 关键词:多孔氮化硅陶瓷;制备方法;物理性能;化学稳定性;应用前景 Introduction 多孔氮化硅陶瓷是一种新型材料,在诸多领域均有可能得到广泛应用。多孔氮化硅陶瓷具有优异的化学稳定性、高温稳定性和机械性能,因此在催化剂载体、高温过滤材料、复合材料等众多领域均有潜在应用。本文将从多孔氮化硅陶瓷的制备方法、物理性能、化学稳定性和应用前景四个方面进行全面的研究和探讨。 PreparationofPorousSiliconNitrideCeramics Thepreparationmethodsofporoussiliconnitrideceramicsmainlyincludepreparationofsiliconnitrideprecursor,templatemethodandsoft-hardmoldpressingmethod. 1.Preparationofsiliconnitrideprecursor Thepreparationofsiliconnitrideprecursorincludesthereactionofsilicaorsiliconpowderandcarbonsource.Generally,thereactiontemperatureishigh,andtheproducedproductisdense. 2.Templatemethod Thetemplatemethodincludesreplicationmethod,sacrificialtemplatemethodandself-templatemethod.Amongthem,thereplicationmethodisthemostcommonlyused.Thebasicprincipleistouseaspecifictemplatematerialtoformanetwork-likeinterconnectedstructureandfillthevoidswithamixtureofsiliconnitriderawmaterials.Afterhightemperaturesinteringandremovalofthetemplate,aporoussiliconnitrideceramicwithacertainstructurecanbeobtained. 3.Soft-hardmoldpressing Theprocessistomixthebinderandsiliconnitridepowderintoapaste,andthenformitintoacertainshapebyusingasoftmold,andthenuseahardmoldtopresstheformedproducttomaketheshape.Generally,thesinteringtemperatureislowerthanthesinteringtemperatureofothermethods. PhysicalPropertiesofPorousSiliconNitrideCeramics Poroussiliconnitrideceramicshaveuniquephysicalproperties,includinghighspecificsurfacearea,highporosity,lowthermalconductivity,andgoodmechanicalproperties.Thesepropertiesmakeporoussiliconnitrideceramicsagoodcandidateforapplicationsinthefieldsofcatalystsupports,ceramicfilters,andcompositematerials. ChemicalStabilityofPorousSiliconNitrideCeramics Poroussiliconnitrideceramicshaveexcellentchemicalstabilityandcanbeusedinharshenvironments,suchashightemperatureandhighpressureenvironments.Poro