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系列Ln-Ag配聚物的合成、晶体结构及发光性能研究.docx

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系列Ln-Ag配聚物的合成、晶体结构及发光性能研究 Title:Synthesis,CrystalStructure,andLuminescentPropertiesofLn-AgCoordinationPolymers:AComprehensiveReview Abstract: Ln-Agcoordinationpolymershaveattractedsignificantattentionduetotheiruniqueopticalpropertiesandpotentialapplicationsinoptoelectronicdevices.Inthisreview,wepresentanoverviewofthesynthesis,crystalstructure,andluminescentpropertiesofLn-Agcoordinationpolymers.Wediscussthevarioussyntheticstrategiesemployedtofabricatethesematerialsandprovideanin-depthanalysisoftheircrystalstructures.Furthermore,wehighlighttheluminescentpropertiesofLn-Agcoordinationpolymersandexploretheirpotentialapplicationsinsensing,imaging,andlightingtechnologies.ThisreviewaimstoprovideacomprehensiveunderstandingofLn-Agcoordinationpolymers,facilitatingfurtheradvancementsintheirdesignandapplications. 1.Introduction Ln-Agcoordinationpolymersexhibitfascinatingopticalpropertiesduetothesynergisticeffectsoflanthanideionsandsilverclusters.TheabilitytotailortheluminescentpropertiesofLn-Agcoordinationpolymersthroughprecisecontrolofsyntheticparametersandstructuralmodificationsmakesthempromisingcandidatesforvariousapplications.ThissectionprovidesabriefintroductiontotheimportanceofLn-Agcoordinationpolymersinthefieldofoptoelectronics. 2.SyntheticStrategies ThissectiondiscussesthevarioussyntheticmethodsemployedtofabricateLn-Agcoordinationpolymers,includingsolvothermalsynthesis,hydrothermalsynthesis,andtemplate-assistedsynthesis.Wehighlighttheroleofdifferentreactionconditionsandprecursorsincontrollingthesize,morphology,andcompositionofLn-Agcoordinationpolymers.Moreover,wediscussthechallengesandfutureperspectivesinthesynthesisofadvancedLn-Agcoordinationpolymers. 3.CrystalStructureAnalysis Inthissection,wepresentanin-depthanalysisofthecrystalstructuresofLn-Agcoordinationpolymers.WefocusonthecoordinationmodesofLnions,thecoordinationgeometriesofAgclusters,andtheintermolecularinteractionsinthesepolymers.CrystallographicdataobtainedviaX-raydiffractionandothercharacterizationtechniquesa