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Ga2基Heusler合金的物性探索 摘要 Ga2基Heusler合金是一种具有广泛应用前景的新型多功能材料,其具有良好的磁性、超导性、电特性和力学性能。本文以文献调研为基础,综合分析了Ga2基Heusler合金的物性研究进展,包括电性、磁性、力学性和超导性等方面的研究现状和发展趋势。根据现有文献,我们认为磁性和电性是Ga2基Heusler合金的主要研究方向,其中主要包括Co2MnGe、Fe2VAl等。另外,目前对于Ga2基Heusler合金磁性的理论模拟和计算也在不断发展中。随着技术的进步和研究的深入,Ga2基Heusler合金有望在磁存储、储能、传感、热电、光电领域中发挥重要作用。 关键词:Ga2基Heusler合金,电性,磁性,力学性质,超导性。 Introduction HeusleralloyisaternaryintermetalliccompoundwiththeformulaX2YZ,whereXandYaretransitionmetalsandZisamaingroupelement.Ga2-basedHeusleralloyshaveattractedconsiderableattentionduetotheirpromisingpropertiesinelectronicandmagneticapplications.Inthispaper,wereviewtherecentprogressinthestudyofGa2-basedHeusleralloys,includingelectrical,magnetic,mechanical,andsuperconductingproperties. ElectricalProperties TheelectricalpropertiesofGa2-basedHeusleralloyshavebeenstudiedextensively.Co2MnAlandCo2MnSiexhibithalf-metallicbehavior,whichisapromisingfeatureforspintronicapplications.ThebandstructurecalculationshowsthattheFermilevelofthesealloysislocatedwithinthespin-polarizedmajorityband,whichreducesspin-flipscatteringandenhancesspin-polarizedcurrenttransport.Inaddition,Fe2VAlandNiMnSbexhibitexcellentthermoelectricproperties,withahighfigureofmerit(ZT)ofupto1.6and1.4,respectively.ThehighZTvaluescanbeattributedtothelowthermalconductivityandhighelectricalconductivityofthesealloys. MagneticProperties ThemagneticpropertiesofGa2-basedHeusleralloyshavebeenextensivelystudiedduetotheirpotentialapplicationsinspintronicdevices,magneticrecording,andsensors.Amongthem,Co2MnGeandFe2VAlhavebeenwidelyresearched.Co2MnGeisaferrimagnetwithahighCurietemperature(Tc=700K)andexhibitsalargeexchangefieldinmagnetictunneljunctions.Fe2VAlisaferromagnetwithahighsaturationmagnetization(Ms=4μB/f.u.)andCurietemperature(Tc=580K),whichmakesitapromisingcandidateformagneticdatastorage. MechanicalProperties ThemechanicalpropertiesofGa2-basedHeusleralloyshavebeenstudiedtoassesstheirpotentialforstructuralapplications.Co2MnSiwasfoundtoexhibithighfatiguestrength,whichmakesitapromisingmateri