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土壤重金属含量测定不同消解方法的对比分析 Title:ComparativeAnalysisofDifferentDigestionMethodsforHeavyMetalDeterminationinSoilSamples Abstract: Soilcontaminationbyheavymetalsposesasignificantthreattoenvironmentalhealthandhumanwell-being.Therefore,accuratedeterminationofheavymetalcontentinsoilisessentialtoassessthepotentialrisksassociatedwithcontaminatedareas.Thisstudyaimstocompareandanalyzedifferentdigestionmethodscommonlyusedforthedeterminationofheavymetalcontentinsoilsamples.Thedigestionmethodsunderinvestigationincludeaciddigestion,microwavedigestion,andhybriddigestion.Thecomparativeanalysisexaminesvariousfactorslikeefficiency,accuracy,cost-effectiveness,andsafetyofthesemethods.Thefindingsofthisstudywillprovideacomprehensiveinsightintothesuitabilityofdifferentdigestionmethodsforheavymetalanalysisinsoil. 1.Introduction: Soilcontaminationwithheavymetalsisagrowingconcernworldwideduetoanthropogenicactivitiessuchasmining,industrialprocesses,andimproperwastedisposal.Heavymetalscanaccumulateinthesoil,posinghazardstoecosystems,crops,andhumanhealth.Therefore,theaccuratedeterminationofheavymetalcontentinsoiliscrucialforeffectiveenvironmentalmanagementandriskassessment. 2.DigestionMethods: 2.1AcidDigestion: Aciddigestionisoneofthetraditionalandwidelyusedmethodsforheavymetaldeterminationinsoilsamples.Inthismethod,soilsamplesaredigestedusingstrongacids,typicallyamixtureofhydrochloricacid(HCl)andnitricacid(HNO3).Aciddigestionaimstodissolvethevarioussoilcomponents,releasingtheheavymetalsintoasolutionsuitableforsubsequentanalysis.Thismethodisrelativelysimple,cost-effective,andwidelyavailable.However,aciddigestionmaynotcompletelydissolveallheavymetalspeciesinthesoilmatrix,leadingtoinaccuratemeasurements. 2.2MicrowaveDigestion: Microwavedigestionisamoreadvancedandefficientmethodforheavymetaldetermination.Itinvolvestheuseofmicrowaveradiationtorapidlyheatthesoilsamplesinaclosedvesselcontaininganappropriatedigestionsolution.Thecontrolledheatingandpressurizedconditionsensurethoroughdigestionofthesoilmatrix