金属卟啉仿生催化烯烃环氧化的性能及机理研究的开题报告.docx

金属卟啉仿生催化烯烃环氧化的性能及机理研究的开题报告
摘要：
随着环境污染问题的日益严重，化学合成方法的发展也越来越注重环境友好、效率高、选择性强的特点。金属卟啉催化烯烃环氧化是一种高效、选择性好、绿色环保的合成方法。本论文主要研究了金属卟啉仿生催化烯烃环氧化的性能与机理，包括催化剂的合成、表征及性能测试。同时，通过反应动力学和理论计算方法对催化机理进行了探究。最终得到了一种高效、选择性好的金属卟啉催化剂。
关键词：金属卟啉；仿生催化；烯烃；环氧化；反应机理
Abstract:
Withtheincreasinglyseriousenvironmentalpollution,thedevelopmentofchemicalsynthesismethodsalsopaysmoreandmoreattentiontoenvironmentalfriendliness,highefficiency,andstrongselectivity.Metalloporphyrincatalyzedepoxideisahighlyefficient,selective,greenandenvironmentallyfriendlysyntheticmethod.Thisthesismainlystudiestheperformanceandmechanismofmetalloporphyrinbiomimeticcatalyzedepoxidationofolefins,includingthesynthesis,characterizationandperformancetestingofcatalysts.Atthesametime,thecatalyticmechanismwasexploredbyreactionkineticsandtheoreticalcalculationmethods,andahighlyefficientandselectivemetalloporphyrincatalystwasobtained.
Keywords:metalloporphyrin;biomimeticcatalysis;olefin;epoxidation;reactionmechanism
1.Introduction
Metalloporphyrin,asanimportantcatalyticmaterial,hasbeenwidelyusedinvariousfieldssuchasorganicsynthesis,environmentalprotection,andpharmaceuticalsduetoitsuniqueelectronicstructureandcatalyticactivity.Amongthem,thecatalyticepoxidationofolefinshasreceivedextensiveattention.Inordertofurtherimprovethecatalyticactivityandselectivityofmetalloporphyrinintheepoxidationreaction,researchershavecarriedoutalotofworkonthepreparationofnewcatalystsandtheexplorationofreactionmechanisms.
2.ResearchObjectives
Themainobjectivesofthisstudyare:
(1)Tosynthesizeandcharacterizeaseriesofmetalloporphyrincatalysts;
(2)Toinvestigatetheperformanceofmetalloporphyrincatalystsintheepoxidationofolefins;
(3)Toexplorethereactionmechanismsofmetalloporphyrin-catalyzedepoxidationofolefinsbykineticandtheoreticalcalculations.
3.ResearchPlan
Theresearchplanmainlyincludesthefollowingaspects:
(1)Synthesisandcharacterizationofmetalloporphyrincatalysts:ThemetalloporphyrincatalystissynthesizedbyacommonmethodandcharacterizedbyUV-Vis,IR,NMRandMS.
(2)Performance