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热氧化背面钝化晶硅电池工艺的探究 鲁贵林1,2,周利荣2,沈文忠1 1上海交通大学太阳能研究所200240上海 2上海神舟新能源发展有限公司201120上海 Outlook 1.StructureofthePERC-typesolarcells 2.ProcessflowofthePERC-typesolarcells 3.Relevantdataanalysis 4.Conclusions 5.Acknowledgements 1.StructureofthePERC-typesolarcells DifferencesbetweenConventionalsolarcells(left)and PERC-typesolarcells(right) 2.ProcessflowofthePERC-typesolarcells 6’FZp-Siwafer,0.5-3Ω•cm,150-180μm Texturing Diffusion NoALDequipment EdgeisolationandPSGetch FSFPECVDSiNxTherm-oxidationSiOx ScreenprintingFSF/BSFPECVDSiNx SinteringBSFLasergrooving TestingandSortingScreenprintingEtchingpaste Sintering TestingandSorting 2-1.Differentthermaloxidationprocess Groups RPSA1RPSA2RPSA3RPSA4RPSA5 Parameters Temperatures/℃700800800800700 Time/h42343 2-2.τandVocatvariousthermaloxidationprocess 2-2-1.Minoritycarrierlifetimeτ/μs 2-2-2.Open-circuitVoltageVoc/V 2-3.Thesurfacetopographyafterlaserablation Laserparameters:dual-pulse,frequency-200kHz,power-3.7W, velocity-4m/s,groovewidth-40μm,groovepitch-1mm 3.Relevantdataanalysis 3-1.Theopen-circuitvoltage(Voc)andtheshort-circuitcurrent(Isc) 3-2.Theseriesresistance(Rs)andtheshuntresistance(Rsh) 3-3.Thefillfactor(FF)andtheconversionefficiency(Eff) 3-4.Theperformanceparametersofthevarioussamples Parameters Voc/VIsc/AFF/%Eff/%Rs/mΩRsh/ΩEff-Max/%Eff-Min/% Groups RPSA10.6499.03278.3519.263.09118.3619.4319.02 RPSA20.6538.98878.0119.203.2192.0219.3618.89 RPSA30.6569.06177.9719.393.43192.2119.5019.26 RPSA40.6499.02378.2219.223.1892.8519.4019.03 RPSA50.6508.92978.3419.073.1378.5819.2418.68 3-5.EQEofthePERC-typesolarcell 4.Conclusions Ⅰ.Comparedwiththeconventionalsolarcells,theVoc,Isc,EFFand EQEwereimprovedgreatly,passivationeffectisremarkable. Ⅱ.Matchedwiththethermaloxidationmethod,lasergrooving, FSF/BSFPECVD,Screen-printing(SP)aluminumpasteand sinteringshouldbechangedaccordingly. Ⅲ.Inordertoachieveproductionrequirements,thismethodshouldbe furtheroptimized. 5.Acknowledgements Theauthorswouldli